Silicone Fabrication Q&A
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My question relates to the effect of radiation (gamma, E-beam) on a silicone material, specifically LSRs and HCRs. What technologies are available to combat radiation-induced methyl-to-methyl cross-linking between surfaces in contact with each other? The end result is that molded parts can stick to themselves. Are there any additives or processes that could be employed to minimize or eliminate the free radical generation or the effects of the free radicals?Answered August 5th, 2010 by Expert:Sticking parts can definitely be an issue, especially with lower-durometer molded parts. The first thing I would suggest trying is to perform a postcure at ~350°–400°F for two to four hours after molding. This finishes most of the cross-linking that may be occurring after molding and is occurring during your gamma-radiation period in your application. An additive that helps with lubricity but may also be an issue in your application is a filler to add to the silicone. I know that Zonyl (Teflon), which is sometimes used to create lubricity within molded silicone components, would reduce sticking and cross-linking between two like materials. Generally a mixed ratio of ~10–15% Zonyl by weight is a sufficient loading. But I would try the postcure first.

